The Secret Hazards of Pesticides:Inert IngredientsAttorney General of New York
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Table 1: Percent Inerts in a Sampling of Pesticide Products(4) | ||
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HOUSEHOLD PESTICIDE | MANUFACTURER | PERCENT INERT |
Ant, Roach, and Spider Killer | Dexol Industries | 99.5 |
Aphid and Mite Attack | Ringer Corp. | 97.96 |
Crawling Insect Attack | Ringer Corp. | 99.56 |
Flea Kill Fogger | The d-Con Co. Inc. | 98.35 |
Hyponex Bug Spray | Hyponex Corp. | 99.78 |
Insecticidal Soap for Indoor Plants | Safer, Inc. | 98.0 |
Mite Killer | Safer, Inc. | 98.0 |
No-Roach | Gaston Johnston Corp. | 82.034 |
Ortho Flea-B-Gon | Chevron Chemical Co. | 99.17 |
Ortho Hi-Power Ant, Roach & Spider Killer | Chevron Chemical Co. | 95.11 |
Ortho Hornet & Wasp Killer | Chevron Chemical Co. | 99.50 |
Raid Ant & Roach Killer | S.C.Johnson & Sons Inc. | 99.10 |
Raid Flying Insect Killer | S.C.Johnson & Sons Inc. | 99.2 |
Raid Fogger II | S.C.Johnson & Sons Inc. | 85.0 |
Raid Fumigator | S.C.Johnson & Sons Inc. | 87.4 |
Raid House and Garden Bug Killer | S.C.Johnson & Sons Inc. | 97.504 |
Spectracide Garden, Rose & Household Plant Spray | Kenco Chem. & Mfg. Corp. | 99.5 |
Spectracide Home Insect Control | Kenco Chem. & Mfg. Corp. | 99.17 |
Spectracide Indoor Fogger | Kenco Chem. & Mfg. Corp. | 99.40 |
Spectracide Wasp and Hornet Killer | Kenco Chem. & Mfg. Corp. | 99.3664 |
Wasp and Hornet Attack | Ringer Corp. | 99.56 |
LAWN CARE FUNGICIDE | ||
Lawn and Turf Fungicide | Faesy & Besthoff, Inc. | 92.0 |
Lawn Disease Preventer | Glorion Corp. | 95.0 |
Lawn Fungicide | Lebanon Chemical Corp. | 99.945 |
LAWN CARE HERBICIDE | ||
2-Way Green Power | Lebanon Chemical Corp. | 96.52 |
Balan 2, 5G | Elanco Products Co. | 97.5 |
Expel Dandelion Killer | Lebanon Chemical Corp. | 97.92 |
Longlife Weed and Feed | Frank's Nursery & Crafts | 99.9845 |
Preen'n Green | Lebanon Chemical Co. | 99.26 |
Spectracide Grass and Weed Killer | Kenco Chem. & Mfg. Corp. | 99.7 |
Step 1 Crab Grass Prevention | O.M.Scott & Sons Co. | 99.85 |
Step 2 Weed Control | O.M.Scott & Sons Co. | 97.205 |
Super Turf Builder Plus 2 | O.M.Scott & Sons Co. | 97.66 |
Super Turf Builder Plus Halts | O.M.Scott & Sons Co. | 98.97 |
Surety Weed and Feed Plus | Howard Johnson Ent. Inc. | 99.063 |
Team 2G | Elanco Products Co. | 98.0 |
XL 2G | Elanco Products Co. | 98.9 |
LAWN CARE INSECTICIDE | ||
Bugout | Lebanon Chemical Corp. | 98.86 |
Chinch Bug & Grub Preventer | Glorion Corp. | 97.28 |
Deluxe Weed and Feed | Glorion Corp. | 97.28 |
Grub Buster | Free Flow Fertilizer | 98.5 |
Insect Control | O.M.Scott & Sons Co. | 96.40 |
Lawn Insect Control | Glorion Corp. | 98.86 |
Lawn Insect Control | O.M.Scott & Sons Co. | 94.16 |
Lawn Insecticide | Free Flow Fertilizer | 95 |
Lawn Insecticide | Greensweep Household Products | 58.5 |
LAWN CARE INSECTICIDE | MANUFACTURER | PERCENT INERT |
Longlife Lawn & Garden Insecticide | Frank's Nursery & Crafts | 95.000 |
Oftanol | Glorion Corp. | 98.5 |
Spectracide Lawn & Garden Insect | Kenco Chem. & Mfg. Corp. | 95 |
Control (granular) | ||
Spectracide Lawn & Garden | Kenco Chem. & Mfg. Corp. | 18.7 |
Insect Control (liquid) | ||
Step 3 Insect Control | O.M.Scott & Sons Co. | 96.40 |
GENERAL HERBICIDES | ||
2 in 1 Crabgrass Preventer | Glorion Corp. | 98.78 |
AAtrex 4L | CIBA-GEIGY Corp. | 57.0 |
Arsenal | American Cyanamid Co. | 72.4 |
Chopper | American Cyanamid Co. | 72.4 |
Ortho Kleenup Super Edger | Chevron Chemical Co. | 99.50 |
Prowl | American Cyanamid Co. | 57.7 |
GARDEN FUNGICIDE | ||
Dexol Bordeaux Mixture | Dexol Industries | 87.35 |
Garden Fungicide | Safer, Inc. | 99.6 |
Pipron L.C. | Elanco Products Co. | 17.6 |
Rubigan E.C. | Elanco Prodcuts Co. | 87.5 |
GARDEN INSECTICIDE | ||
Liquid Sevin | Faesy & Besthoff, Inc. | 77.5 |
Ortho 3-Way Rose & Flower Care | Chevron Chemical Co. | 98.85 |
Rose & Flower Spray or Dust | Bonide Chemical Co. Inc. | 84.5 |
Spectracide Rose & Garden Insect Killer | Kenco Chem. & Mfg. Corp. | 99.88 |
OUTDOOR INSECTICIDE | ||
Abate 1-SG | American Cyanamid Co. | 99 |
Amdro | American Cyanamid Co. | 99.12 |
Cygon 400 | American Cyanamid Co. | 56.5 |
Gypsy Moth Biological Control | Acme Burgess Inc. | 99.14 |
Mosquito Attack | Ringer Corp. | 50 |
Ortho Diazinon Soil & Foliage Dust | Chevron Chemical Co. | 96 |
Ortho Diazinon Plus Insect Spray | Chevron Chemical Co. | 75 |
Ortho Home Orchard Spray | Chevron Chemical Co. | 62.5 |
Ortho Isotox Insect Killer | Chevron Chemical Co. | 90.6 |
Ortho Orthene Systemic Insect Control | Chevron Chemical Co. | 90.6 |
Ortho Rose & Flower Insect Killer | Chevron Chemical Co. | 99.70 |
Ortho Sevin | Chevron Chemical Co. | 95 |
Raid Yard Guard | S.C.Johnson & Sons Inc. | 99.125 |
Yard and Garden Insect Attack | Ringer Corp. | 99.56 |
PET CARE | ||
Hartz 2 in 1 Flea and Tick | The Hartz Mountain Corp. | 99.332 |
INSECT REPELLENT | ||
Cutter Insect Repellent | Miles Laboratory | 67 |
Off | S.C.Johnson & Sons Inc. | 85.00 |
Ortho Outdoor Insect Fogger | Chevron Chemical Co. | 91.385 |
MOLLUSCICIDE | ||
Deadline | Pace National Corp. | 96 |
Ortho Slug-geta | Chevron Chemical Co. | 98 |
Table 2. Some Adverse Health Effects Of Certain Inert Pesticide Ingredients | |
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Chemical | Effects |
Carbon tetrachloride* | Irritation of skin, eyes nose, throat; dizziness, vomiting, abdominal pain; diarrhea; damage to kidneys, liver; central nervous system depression; suspected carcinogen. |
Chlorobenzene* | Eye and skin irritation, burns and inflammation; chest pain, slow heart rate, ECG irregularities; lung, liver and kidney damage; central nervous system depression; coma. |
Chloroform* | Irritation to eyes and gastrointestinal tract; damage to liver and kidneys; central nervous system depression; nausea, dizziness, fatigue, respiratory distress; gonadal atrophy; fetal resorption; mutagen; coma and death by cardiac arrest; suspected carcinogen. |
Chloroethane | Irritation of eyes; abdominal cramps, nausea, vomiting; liver and kidney damage; nervous system dysfunction; blood cell disorders; suspected carcinogen. |
Cresols | Skin irritation, burns, and inflammation; irritation of eye, permanent damage and blindness; pneumonia; pancreatitis; central nervous system disorders; kidney failure. |
Dibutylphthalate | Irritation of eyes and throat; photophobia, conjunctivitis,nausea, dizziness. |
Diethylhexylphthalate* | Eye, nose and throat irritation; liver damage; testicular damage; central nervous system depression; suspected carcinogen. |
Dimethylphthalate | Irritation of eyes, mouth, nose, throat; dizziness, abdominal pain, nausea, vomiting, diarrhea; central nervous system depression; reduced respiratory rate; paralysis, coma. |
Epichlorohydrin* | Skin and eye irritation, conjunctivitis, corneal clouding; nausea, vomiting, fatigue; liver and kidney damage; inflammation of lungs, chronic bronchitis; death by respiratory paralysis; mutagen; fetotoxic. |
Ethylbenzene | Irritation of eyes, nose and throat; skin irritation, inflammation, blisters and burns; liver and kidney damage; central nervous system disorders; headache, sleepiness, difficulty in breathing; unconsciousness and coma. |
Ethylene dichloride* | Nausea, vomiting, diarrhea; damage to liver and kidneys; central nervous system depression; death due to circulatory and respiratory failure. |
Isophorone | Irritation of skin, nose, throat, respiratory system; lung congestion and degeneration; central nervous system disorders; kidney and liver damage; suspected carcinogen. |
Methyl bromide* | Eye and skin irritation; blurredvision, headache, dizziness, nausea, abdominal cramps; anorexia; bronchopneumonia, pulmonary edema; brain damage, convulsions, coma; kidney and respiratory failure. |
o-Dichlorobenzene | Eye irritation and cataracts; skin irritation and lesions; headache, nausea, vomiting, drowsiness; respiratory depression; anemia, kidney and liver damage; chromosomal breaks. |
p-Dichlorobenzene | Irritation of skin, eyes, respiratory system; headache, dizziness, hyperactivity, weakness, weight loss; liver and blood disorders; kidney damage; lung congestion, difficulty in breathing; mutagen. |
Phenol | Irritation of eyes, nose, throat; headache, dizziness, fainting, abdominal pain, nausea, vomiting, diarrhea; damage to liver, kidney and heart; chromosomal aberrations and damage; mutagen. |
Propylene dichloride* | Eye and skin irritation; dizziness, disorientation, nausea, vomiting; liver and kidney damage; central nervous system damage; coma; hemolytic anemia; suspected carcinogen. |
1,1,2-Trichloroethane* | Gastrointestinal inflammation and congestion; liver and kidney damage; immune function disorder; central nervous system depression; suspected carcinogen. |
Toluene | Skin, eye and respiratory irritation; abdominal pain, headache, nausea, dizziness, drowsiness, hallucinations; anemia; liver disorders and enlargement; central nervous system dysfunction; coma and death. |
Trichloroethylene* | Eye irritation, visual distortion; abdominal pain, nausea, diarrhea; anorexia; liver and kidney damage; peripheral nerve damage, numbness and paralysis; blood disorders; cardiac arrhythmia; suspected carcinogen. |
*This chemical was identified as an Inert Ingredient by EPA in 1991, but is absent from the most current list of Inert Ingredients released in May, 1995.
Sources:
U. S. Environmental Protection Agency, Chemical Profiles, Interim Guidance, Chemical Emergency Preparedness Program, 1985
U. S. Environmental Protection Agency, Office of Health and Environmental Assessment, Health Assessment Documents
U. S. Public Health Service, Agency for Toxic Substances and Disease Registry, Toxicological Profiles
New York State Department of Health, Chemical Fact Sheets
TABLE 3. A GUIDE TO SELECTED REGULATIONS COVERING CHEMICALS ALSO USED AS INERTS.*
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Number of ___________________________________________________________________REGULATIONS AND ADVISORIES**_____________________________________________________________________
Applicable
Regulations/ SDWA TSCA CERCLA/SARA RCRA CWA OSHA NTP ACGIH IARC DOT CAA NIOSH
Chemical | Advisories | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 | 21 | 22 | 23 | 24 | 25 | 26 |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Chloroform | 21 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||
p-Dichlorobenzene | 21 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||
Ethylene dichloride | 20 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | ||||||
Carbon tetrachloride | 19 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||
Chlorobenzene | 19 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||
o-Dichlorobenzene | 19 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||
Propylene dichloride | 19 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||
Trichloroethylene | 17 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||||
Methyl bromide | 16 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | ||||||||||
Toluene | 16 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | ||||||||||
1,1,2-Trichloroethane | 15 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||||||
Diethylhexylphthalate | 15 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||||||
Epichlorohydrin | 15 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||||||
Phenol | 15 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||||||
Chloroethane | 14 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | ||||||||||||
Dibutylphthalate | 14 | X | X | X | X | X | X | X | X | X | X | X | X | X | X | ||||||||||||
Dimethylphthalate | 13 | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||||||||
Ethyl benzene | 13 | X | X | X | X | X | X | X | X | X | X | X | X | X | |||||||||||||
Cresols | 12 | X | X | X | X | X | X | X | X | X | X | X | X | ||||||||||||||
Isophorone | 11 | X | X | X | X | X | X | X | X | X | X | X |
* Adapted from: Suspect Chemicals Sourcebook, K.b. Clansky, Ed., 1989 Edition
(Updated to Jan. 1, 1990) Roytech Publications, Inc.
** See "Explanation of Regulations and Advisories" which follows for specific identification.
1. Maximum Contaminant Levels (MCL)
Requires the U. S. Environmental Protection Agency (EPA) to establish primary drinking water regulations which 1) apply to public water systems, 2) specify contaminants which may have adverse health effects, 3) specify Maximum Contaminant Levels (MCL, the maximum permissible level of a contaminant in water) or treatment techniques for each listed contaminant, 4) establish public notification requirements.
2. Maximum Contaminant Level Goals
Establishes non-enforceable Maximum Contaminant Level Goals (MCLG) which are set at a level at which no known or anticipated adverse health effects occur and which provide an adequate margin of safety.
3. Monitoring Requirements
Requires monitoring for contaminants likely to be found in the system's drinking water, including contaminants not regulated under National Primary Drinking Water Regulations. Results must be reported to both the State and EPA and made available to the public.
4. 1986 Amendments/Statutory Contaminants
Requires EPA to regulate 83 contaminants by publishing MCLG's and promulgating National Primary Drinking Water Regulations for each of the 83 listed contaminants.
5. 1986 Amendments/Drinking Water Priority List
Requires EPA to establish a priority list of contaminants which may have adverse health effects and are known or anticipated to occur in public water systems.
6. Section 4(a), Final Test Rules
Requires EPA to test substances which meet certain criteria, such as those which may present an unreasonable risk or injury to health or environment, in order to develop health or environmental data.
7. Section 8(d), Health and Safety Data Rule
Requires manufacturers, importers and processors of listed substances to submit to EPA copies and lists of unpublished health and safety studies on the listed substances with which they deal.
8. Section 4(a), Dioxins/Furans Rule
Requires manufacturers and importers of certain organic chemicals to test for the presence of halogenated dibenzodioxins (HDD) and halogenated dibenzofurans (HDF) as contaminants. Results and existing test data must be submitted as well as additional information if HDD and/or HDF concentrations exceed designated levels.
9. Section 12(b), Export Regulations
Requires exporters of chemical substances to notify EPA of such exportation if any exported substances are affected by TSCA Sections 4, 5, 6 or 7.
10. CERCLA. Hazardous Substances
Establishes a list of substances which must be reported to the National Response Center when released
in quantities exceeding a specified reportable quantity.
11. SARA. Title III Section 302 and 304, Extremely Hazardous Substances
Requires facilities handling substances named on the list of extremely hazardous substances to notify the State of the presence of these substances in excess of their Threshold Planning Quantities and must notify local authorities of their release in excess of their Reportable Quantities.
12. SARA. Title III Section 313, Toxic Chemicals
Establishes a list of toxic chemicals. Manufacturers, processors and users of these chemicals must submit release reporting forms.
13. CERCLA Section 104(i), Priority list of CERCLA Hazardous Substances
Requires EPA and the Agency of Toxic Substance and Disease Registry to 1) prepare a prioritized list of hazardous substances commonly found at National Priorities List sites which pose the greatest potential health risk, 2) to develop Toxicological Profiles of these substances, 3) establish a research program to fill data gaps.
14. Requires notification of EPA by anyone who generates, transports, treats, stores or disposes of wastes
specified under Section 3001 of RCRA.
15. Hazardous Constituents for Groundwater Monitoring
Requires groundwater monitoring at RCRA land-based hazardous waste disposal units for all constituents
listed in Appendix IX to 40 Code of Federal Regulations (CFR) 264.
16. Land Disposal Prohibitions - Halogenated Organic Compounds
Restricts land disposal of waste containing halogenated organic compounds above specified concentrations.
17. Land Disposal Prohibitions
Lists the hazardous wastes identified in 40 Code of Federal Regulations 261 which were scheduled for restricted/prohibited land disposal after enactment of the Hazardous and Solid Waste Amendments to RCRA in 1984.
18. Section 304, Water Quality Criteria; Section 307, Priority Pollutants
Requires EPA to publish and periodically update ambient water quality criteria. Criteria are to reflect latest scientific knowledge on the identifiable effects of substances on public health and welfare, including but not limited to aquatic life, aesthetics and recreation. Establishes a list of toxic pollutants for which EPA is required to publish ambient water quality criteria. Under Section 304, these chemicals shall be subject to effluent limits resulting from the application of best available technology.
19. Section 311, Hazardous Chemicals
Requires EPA to publish a list of substances that are considered hazardous if spilled in navigable waters.
20. Air Contaminants (29 CFR 1910.1000)
Establishes a list of air contaminants and sets exposure limits for the workplace.
21. Report on Carcinogens
Identifies carcinogens and subdivides them into Known and Anticipated. Categorizes 162 substances on this basis.
22. Threshold Limit Value Chemicals
Provides various workplace exposure limits (time-weighted average, short-term exposure limits, ceiling limits) for each covered substance.
23. Human Carcinogens (Groups 1, 2A, and 2B)
Identifies carcinogens and classifies them as: Group 1 (sufficient evidence of human carcinogenicity); Group 2A (probable human carcinogen); Group 2B (possible human carcinogen).
24. Hazardous Materials
Regulates interstate commerce of hazardous materials, including all CERCLA hazardous substances, Specifies requirements for description, shipping names, class, labeling and packaging, as well as spill notification.
25. Section 111, Potential Human Health Hazards
Lists substances published by EPA pursuant to Section 111 of the Clean Air Act, which pose a potential health hazard and for which specific control techniques are defined.
26. Criteria Documents
Specifies a NIOSH Recommended Exposure Limit and appropriate preventive measures to reduce or eliminate adverse health effects.
1. "Inert Ingredients in Pesticides," USEPA, Office of the Inspector General, Audit Report E1EPF1-05-0117-1100378, Sept. 27, 1991.
2. Memo from Michael Simmons, Associate Assistant Inspector General for Internal and Performance Audits to Victor J. Kimm, Acting Assistant Administrator for Prevention, Pesticides and Toxic Substances, September 17, 1993. See Foreword for an update on the computer database.
3. FIFRA, Section 10(d)(1)(C), entitled, "Protection of Trade Secrets and Other Information".
4. Based on a market survey conducted during the spring and summer of 1990.
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