Excerpts from Steve Tvedten's book "The Best Control
(2nd Edition)"
Intelligent Pest Management® Mound Treatments
Treating individual fire ant mounds is time consuming, but it is generally
the most effective method of control. It takes from a few hours to
a few weeks to “kill” the mound, depending on the product used. Individual
mound treatment is usually most effective in the spring. The key
is to locate and treat all the mounds in the area to be protected, not
always a simple task. If many young mounds are missed, reinfestation
of the area can take place in less than a year. The following discussions
describe different ways to treat individual mounds.
Fire Ant Mound Drench
Coke. Take two (2) 2-liter bottles of Coca-Cola and pour directly into (a hole) in each mound.
Carbon Dioxide (CO2). Insert several pounds of dry ice or inject the dense gas which is one and a half times heavier than air (use a 20# cylinder of CO2 with 12 foot of hose and a 3’ - 4’ pipe attached) into the fire ant mound and it moves downward killing all worker ants, larvae and the queen. There is no odor or warning as the CO2 gas silently replaces the air in the entire chamber and any connecting tunnels or chambers or mounds. CO2 is not harmful to plants or lawns and after killing the fire ants in the mound, CO2 returns back into the air. Fire ants do not like frozen ground.
Carbon Monoxide (CO) created by burning charcoal briquettes will also control fire ants if you throw them into a hole in the mound with a 2’+ wall (e.g., half of a barrel, open on both ends) around the mound/hole. Propane and other heavier than air gases will also work, but are certainly not as safe.
WAR: take two shovels, dust the handles, your shoes, your socks, and trouser bottoms with talcum powder; get a shovel full of each mound and transfer each shovel full to the another mound and let the ants fight it out among themselves.